1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide-UP

Name: 1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide-UP
SKU: IL-0035-UP
Availability: InStock

$91.50 – $1,189.50

Product Code: IL-0035-UP

CAS NO: 223437-11-4

Chemical Formula: C11H20F6N2O4S2
Synonyms: BMP-BTI, BMPyrr BTA, BMPyrr NTf2, BMPyrr TFSI, BMPyrr BTI, BMPyrr TFSI, Pyr14TFSI, N-Butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

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TDS
CoA

Category: Ionic Liquids Pyrrolidinium

SUM Formula: C11H20F6N2O4S2
Molecular Weight: 422.41
Melting Point: -18 °C
Density: 1.40 g/cm³
ECW: 5.5V
Viscosity: 94.4 cP

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Related Publications
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Related Publications

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide-UP (CAS NO: 223437-11-4)

Topic: Energy storage; batteries; super capacitors; Li-ion batteries; sodium batteries

Papović, S.; Vraneš, M.; Tot, A.; Szilágyi, I.; Katana, B.; Alenezi, K.; Gadžurić, S. Physicochemical Investigations of a Binary Mixture Containing Ionic Liquid 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide and Diethyl Carbonate. J. Chem. Eng. Data 2020, 65 (1), 68–80.

Neale, A. R.; Schütter, C.; Wilde, P.; Goodrich, P.; Hardacre, C.; Passerini, S.; Balducci, A.; Jacquemin, J. Physical-Chemical Characterization of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(Trifluoromethyl)Sulfonyl}imide and Aliphatic Nitrile Solvents as Potential Electrolytes for Electrochemical Energy Storage Applications. J. Chem. Eng. Data 2017, 62 (1), 376–390.

Schütter, C.; Neale, A. R.; Wilde, P.; Goodrich, P.; Hardacre, C.; Passerini, S.; Jacquemin, J.; Balducci, A. The Use of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(Trifluoromethyl)Sulfonyl}imide and Aliphatic Nitrile Solvents as Electrolyte for Supercapacitors. Electrochim. Acta 2016, 220, 146–155.

Lindner, J.; Weick, F.; Endres, F.; Schuster, R. Entropy Changes upon Double Layer Charging at a (111)-Textured Au Film in Pure 1-Butyl-1-Methylpyrrolidinium Bis[(Trifluoromethyl)Sulfonyl]Imide Ionic Liquid. J. Phys. Chem. C 2020.

Wang, E.; Niu, Y.; Yin, Y. X.; Guo, Y. G. Manipulating Electrode/Electrolyte Interphases of Sodium-Ion Batteries: Strategies and Perspectives. ACS Materials Letters. American Chemical Society January 4, 2021, pp 18–41.

Zhang, W.; Ghamouss, F.; Mery, A.; Lemordant, D.; Dedryvère, R.; Monconduit, L.; Martinez, H. Improvement of the Stability of TiSnSb Anode under Lithiation Using SEI Forming Additives and Room Temperature Ionic Liquid/DMC Mixed Electrolyte. Electrochim. Acta 2015, 170, 72–84.

Kim, J.; Weber, I.; Buchner, F.; Schnaidt, J.; Behm, R. J. Surface Chemistry and Electrochemistry of an Ionic Liquid and Lithium on Li ₄ Ti ₅ O ₁₂ (111)—A Model Study of the Anode|electrolyte Interface. J. Chem. Phys. 2019, 151 (13), 134704.

Yan, S.; Wang, Y.; Chen, T.; Gan, Z.; Chen, S.; Liu, Y.; Zhang, S. Regulated Interfacial Stability by Coordinating Ionic Liquids with Fluorinated Solvent for High Voltage and Safety Batteries. J. Power Sources 2021, 491, 229603.

Tiruye, G. A.; Muñoz-Torrero, D.; Palma, J.; Anderson, M.; Marcilla, R. Performance of Solid State Supercapacitors Based on Polymer Electrolytes Containing Different Ionic Liquids. J. Power Sources 2016, 326, 560–568.

Topic: Oxygen reduction reactions

Vainikka, T.; Figueiredo, M. C.; Kontturi, K.; Murtomäki, L. Studies of Oxygen Reduction in 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide by Microdisk Voltammetry. Electrochim. Acta 2015, 156, 60–69.

Azaceta, E.; Marcilla, R.; Mecerreyes, D.; Ungureanu, M.; Dev, A.; Voss, T.; Fantini, S.; Grande, H. J.; Cabañero, G.; Tena-Zaera, R. Electrochemical Reduction of O2 in 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethanesulfonyl)Imide Ionic Liquid Containing Zn2+ Cations: Deposition of Non-Polar Oriented ZnO Nanocrystalline Films. Phys. Chem. Chem. Phys. 2011, 13 (29), 13433–13440.

Bozorgchenani, M.; Fischer, P.; Schnaidt, J.; Diemant, T.; Schwarz, R. M.; Marinaro, M.; Wachtler, M.; Jörissen, L.; Behm, R. J. Electrocatalytic Oxygen Reduction and Oxygen Evolution in Mg‐Free and Mg–Containing Ionic Liquid 1‐Butyl‐1‐Methylpyrrolidinium Bis (Trifluoromethanesulfonyl) Imide. ChemElectroChem 2018, 5 (18), 2600–2611.

Topic: Electrodeposition, electroplating; metal alloys

Thomas, S.; Kowalski, D.; Molinari, M.; Mallet, J. Role of Electrochemical Process Parameters on the Electrodeposition of Silicon from 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethanesulfonyl)Imide Ionic Liquid. Electrochim. Acta 2018, 265, 166–174.

Vacca, A.; Mascia, M.; Mais, L.; Delogu, F.; Palmas, S.; Pinna, A. Electrodeposition of Zirconium from 1-Butyl-1-Methylpyrrolidinium-Bis(Trifluoromethylsulfonyl)Imide: Electrochemical Behavior and Reduction Pathway. Mater. Manuf. Process. 2016, 31 (1), 74–80.

Ismail, A. S. Electrodeposition of Aluminium–Copper Alloy from 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl) Imide Ionic Liquid. Egypt. J. Pet. 2017, 26 (1), 61–65.

Maho, A.; Delhalle, J.; Mekhalif, Z. Study of the Formation Process and the Characteristics of Tantalum Layers Electrodeposited on Nitinol Plates in the 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ionic Liquid. Electrochim. Acta 2013, 89, 346–358.

Vacca, A.; Mascia, M.; Mais, L.; Rizzardini, S.; Delogu, F.; Palmas, S. On the Electrodeposition of Niobium from 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide at Conductive Diamond Substrates. Electrocatalysis 2014, 5 (1), 16–22.

Dilasari, B.; Jung, Y.; Kwon, K. Effect of Water on the Stability of Zinc in 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ionic Liquid. J. Ind. Eng. Chem. 2017, 45, 375–379.

Wu, M.; Vanhoutte, G.; Brooks, N. R.; Binnemans, K.; Fransaer, J. Electrodeposition of Germanium at Elevated Temperatures and Pressures from Ionic Liquids. Phys. Chem. Chem. Phys. 2015, 17 (18), 12080–12089.

Topic: CO₂ capture; gas separation

Turnaoglu, T.; Minnick, D. L.; Morais, A. R. C.; Baek, D. L.; Fox, R. V.; Scurto, A. M.; Shiflett, M. B. High-Pressure Vapor-Liquid Equilibria of 1-Alkyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ionic Liquids and CO2. J. Chem. Eng. Data 2019, 64 (11), 4668–4678.

Morais, A. R. C.; Alaras, L. M.; Baek, D. L.; Fox, R. V.; Shiflett, M. B.; Scurto, A. M. Viscosity of 1-Alkyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ionic Liquids Saturated with Compressed CO2. J. Chem. Eng. Data 2019, 64 (11), 4658–4667.

Singh, P.; Tarakeshwar, P.; Buttry, D. A. Experimental, Simulation, and Computational Study of the Interaction of Reduced Forms of N ‐Methyl‐4,4’‐Bipyridinium with CO₂. ChemElectroChem 2020, 7 (2), 469–475.

Ramdin, M.; Amplianitis, A.; Bazhenov, S.; Volkov, A.; Volkov, V.; Vlugt, T. J. H.; De Loos, T. W. Solubility of CO₂ and CH₄ in Ionic Liquids: Ideal CO₂/CH₄ Selectivity. Ind. Eng. Chem. Res. 2014, 53 (40), 15427–15435.

Tomé, L. C.; Mecerreyes, D.; Freire, C. S. R.; Rebelo, L. P. N.; Marrucho, I. M. Pyrrolidinium-Based Polymeric Ionic Liquid Materials: New Perspectives for CO₂ Separation Membranes. J. Memb. Sci. 2013, 428, 260–266.

Topic: Anti-fungal

DiRenzo, G. V.; Chen, R.; Ibsen, K.; Toothman, M.; Miller, A. J.; Gershman, A.; Mitragotri, S.; Briggs, C. J. Investigating the Potential Use of an Ionic Liquid (1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide) as an Anti-Fungal Treatment against the Amphibian Chytrid Fungus, Batrachochytrium Dendrobatidis. PLoS One 2020, 15 (4), e0231811.

Topic: Solvent dehydration; organic synthesis

Cháfer, A.; de la Torre, J.; Lladosa, E.; Loras, S. Study of Liquid–Liquid Equilibria at Different Temperatures of Water + Ethanol + 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ternary System. Fluid Phase Equilib. 2016, 426, 3–9.

Chafer, A.; De La Torre, J.; Lladosa, E.; Pla-Franco, J.; Cumplido, M. P. Liquid-Liquid Equilibria of the Water + 1-Propanol + 1-Butyl-1-Methylpyrrolidinium Bis(Trifluoromethylsulfonyl)Imide Ternary System: Study of the Ability of Ionic Liquid as a Solvent. J. Chem. Eng. Data 2016, 61 (12), 4006–4012.

Cichowska-Kopczyńska, I.; Aranowski, R. Use of Pyridinium and Pyrrolidinium Ionic Liquids for Removal of Toluene from Gas Streams. J. Mol. Liq. 2020, 298, 112091.

Topic: Lubrication

García, A.; González, R.; Hernández Battez, A.; Viesca, J. L.; Monge, R.; Fernández-González, A.; Hadfield, M. Ionic Liquids as a Neat Lubricant Applied to Steel-Steel Contacts. Tribol. Int. 2014, 72, 42–50.

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide [223437-11-4] [BMP] [BTA] is a water and air-stable hydrophobic ionic liquid with a wide electrochemical window of 5.5V It has a viscosity of 95cP at room temperature. [BMP] [BTA] high-temperature stability and wide electrochemical window has resulted in its use in the electro-deposition of various refractory materials and supercapacitors, and it has been evaluated as a lubricant.