Metal Free Battery: Ionic Liquids
Research in the field of ionic liquids (ILs) has increased since their initial discovery in 1914 by Paul Walden. Ionic liquids, salts in liquid state, are frequently described as being liquid below an arbitrary value of 100°C…
Autocatalytic Synthesis of Bifluoride Ionic Liquids by SuFEx Click Chemistry
Ionic liquids with bifluoride anions possess properties such as high conductivity, wide electrochemical windows, and low viscosity that make them…
Ionic liquids and poly(ionic liquid)s for 3D printing – A focused mini-review
Ionic liquids are a class of materials with unique physicochemical properties and intriguing preorganized and tunable solvent structures.
Highly conductive, flexible polymer electrolyte membrane based on poly(ethylene glycol) diacrylate-co-thiosiloxane network
An amorphous co-network consisting of poly(ethylene glycol) diacrylate (PEGDA) and thiosiloxane was prepared by means of thiol-ene “click” reaction to…
Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles
Phosphazene-based polymers were synthesized by using different pendant groups such as trifluoroethoxy (TFE), phenoxy (PHO)…
Cubosomes from hierarchical self-assembly of poly(ionic liquid) block copolymers
Cubosomes are micro- and nanoparticles with a bicontinuous cubic two-phase structure, reported for the self-assembly of low molecular weight…
Highly cross-linked polyether-based 1,2,3-triazolium ion conducting membranes with enhanced gas separation properties
A series of cross-linked polyether-based 1,2,3-triazolium ion conducting membranes are prepared via the combination of thermally promoted Huisgen 1,3-dipolar…
Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry
Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing…
Nanoporous hypercrosslinked polymers containing Tg enhancing comonomers
Hypercrosslinked polymers containing functionalized alternating copolymer sequences of substituted stilbene or styrene and N-aryl substituted…
Phosphazene High Polymers and Models with Cyclic Aliphatic Side Groups: New Structure–Property Relationships
Poly(dichlorophosphazene) is a versatile precursor material for accessing new polymeric materials via the introduction of various side groups by chlorine…
A review of semi-rigid, stilbene-containing alternating copolymers
The synthesis and properties of sterically congested, stilbene-containing alternating copolymers are reviewed.
Eutectic ionic liquid mixtures and their effect on CO2 solubility and conductivity
A simple binary system of compounds resembling short-chain versions of popular ionic liquids has been shown to have surprisingly complex properties.
Branched isomeric 1,2,3-triazolium-based ionic liquids: new insight into structure–property relationships
A series of four isomeric 1,2,3-triazolium-based ionic liquids (ILs) with vary degree of branching were synthesized and characterized to investigate…
Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles
Mixed matrix membranes (MMM) have the potential to overcome the limitations of traditional polymeric membranes for gas separation by improving…
Ionic liquid regioisomers: Structure effect on the thermal and physical properties.
A systematic study was performed on two triazolium ionic liquid isomers which included examination of thermal.
Multifunctional photo-crosslinked polymeric ionic hydrogel films
A facile approach was developed to prepare crosslinked ionic polymer hydrogel films by photo-crosslinking utilizing p-vinylbenzyl trimethylammonium…
Porous polymers prepared via high internal phase emulsion polymerization for reversible CO2 capture
A series of porous polymers with different pore volumes, pore sizes, and crosslinking densities were synthesized by high internal phase emulsion…
Toward a Materials Genome Approach for Ionic Liquids
The Materials Genome Approach (MGA) aims to accelerate development of new materials by incorporating computational and data-driven approaches to reduce the cost of identification.
Clickable poly(ionic liquid)s for modification of glass and silicon surfaces
Covalent attachment of poly(ionic liquid)s (PILs) by click chemistry on glass or silicon (Si) surfaces was performed…
Synthesis and reactivity ratios of regioisomeric vinyl‐1,2,3‐triazoles with styrene
The free radical reactivity ratios between styrene and different vinyl‐1,2,3‐triazole regioisomeric monomers in 1,4‐dioxane at 65 °C have been…
Nanoporous Structure of Semirigid Alternating Copolymers via Nitrogen Sorption and Molecular Simulation
Surface area and porosity of a series of semirigid alternating copolymers consisting of tert-butyl carboxylate-functionalized stilbene…
Understanding the effect of side groups in ionic liquids on carbon-capture properties
Ionic liquids are an emerging class of materials with applications in a variety of fields. Steady progress has been made in the creation of ionic liquids.
Copolymer-templated nitrogen-enriched porous nanocarbons for CO2 capture
Nitrogen-enriched porous carbon materials made via the carbonization of polyacrylonitrile containing block copolymer act as efficient and highly selective CO2 sorbents.
Temperature dependence of dual emission in ruthenium(II) complexes containing 3,3′-bi-1,2,4-triazine derivatives
Three new ruthenium(II) polypyridyl complexes with highly π-deficient ligands, [Ru(bpy)2(btm)]2+ (1), [Ru(bpy)2(btb)]2+ (2) and [Ru(bpy)2(btp)]2+ (3)…
N -Vinyltriazoles: A new functional monomer family through click chemistry
The design of new building blocks and functional units for the construction of macromolecules with novel and/or improved properties…
Molecularly defined (L)‐lactic acid oligomers and polymers: Synthesis and characterization
The synthesis of (L)‐lactide oligomers from dimer to 64mer via an exponential growth strategy is described. By careful selection of orthogonal…
Synthesis and Characterization of Isomeric Vinyl-1,2,3-triazole Materials by Azide−Alkyne Click Chemistry
The synthesis of isomeric, functionalized 4-vinyl-1,2,3-triazole and 5-vinyl-1,2,3-triazole monomers is demonstrated using heterogeneous copper…
Facile syntheses of 4‐vinyl‐1,2,3‐triazole monomers by click azide/acetylene coupling
Synthetic strategies for the preparation of a new family of vinyl monomers, 4‐vinyl‐1,2,3‐triazoles, have been developed.