3-methyl-1-octyl-4-phenyl-triazolium bis((trifluoromethyl)sulfonyl)amide

Product Code: TzPhC8FS

CAS NO: Pending

  • SMILES: O=S(C(F)(F)F)([N-]S(=O)(C(F)(F)F)=O)=O.C[N+](C(C1=CC=CC=C1)=C2)=NN2CCCCCCCC
  • Chemical Formula: C19H26F6N4O4S2

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SUM Formula: C19H26F6N4O4S2

Molecular Weight: 552.55 g/mol

Purity: NA

  • SPECIFIC GRAVITY: 1.3551
  • SUM Formula: C19H26F6N4O4S2
  • Molecular Weight: 552.55 g/mol

3-methyl-1-octyl-4-phenyl-triazolium bis((trifluoromethyl)sulfonyl)amide

Key Applications:

  • 1. Electrochemical Systems

    • Highโ€‘stability electrolyte component in lithium, sodium, and multivalent ion batteries, leveraging the TFSI anionโ€™s wide electrochemical window and the triazolium cationโ€™s thermal robustness.
    • Ionic liquid additive for improving interfacial stability, SEI formation, and highโ€‘temperature cycling performance.
    • Redoxโ€‘active medium for flow batteries and electrochemical reactors where aromatic substitution enhances chargeโ€‘transfer behavior.

    2. Catalysis and Organic Synthesis

    • Nonโ€‘volatile reaction medium for transitionโ€‘metal catalysis, including Cโ€“C and Cโ€“N coupling, where the phenylโ€‘substituted triazolium ring improves catalyst solubility and turnover.
    • Phaseโ€‘transfer catalyst in biphasic systems, benefiting from the long C8 chain and aromatic ring that tune hydrophobicity.
    • Stabilizing medium for carbene generation, particularly Nโ€‘heterocyclic carbene (NHC) chemistry, where triazolium precursors are valued for controlled deprotonation and ligand formation.

    3. Separation Science and Extraction

    • Selective extraction agent for metal ions (e.g., rare earths, transition metals), with the phenyl group enhancing ฯ€โ€‘interactions and the TFSI anion providing low coordinating behavior.
    • Solvent for liquidโ€“liquid extraction of hydrophobic organics, dyes, and aromatic compounds.
    • Stationaryโ€‘phase modifier in chromatography, enabling tunable polarity and enhanced retention of aromatic analytes.

    4. Materials Science and Polymer Integration

    • Plasticizer or ionic dopant in polymer electrolytes, ionogels, and conductive films.
    • Template or structureโ€‘directing agent in nanoparticle synthesis, especially for noble metals where aromatic cations influence particle morphology.
    • Component in selfโ€‘assembled materials, leveraging amphiphilic behavior from the octyl chain and aromatic ring.

    5. Spectroscopy, Sensors, and Analytical Uses

    • Medium for spectroelectrochemical studies, offering high optical transparency and low volatility.
    • Ionic liquid matrix for sensors detecting aromatic pollutants or metal ions, where ฯ€โ€‘stacking enhances analyte affinity.
    • Stabilizing environment for fluorescence and Raman studies requiring low background and high thermal stability.

    6. Highโ€‘Temperature and Vacuum Applications

    • Heatโ€‘transfer and thermalโ€‘stability medium in controlled environments where nonโ€‘flammability and low vapor pressure are essential.
    • Lubrication additive for highโ€‘vacuum or highโ€‘temperature systems, benefiting from TFSIโ€™s chemical inertness.

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Additional information

Weight 2 g
Qty