Publications

  • 2022
    1. Zhou, X.; Nulwala, H.; Portie, M.; Badwe, M.; Medlin, K.; Roberts, D.-L. 3rd Generation, High Performance, Water-Lean Solvents for Carbon Capture. April 6, 2022.
    2. Zhou, X.; Nulwala, H.; Kim, H.; Chen, S. (Scott). Universal Solvent Viscosity Reduction via Hydrogen Bonding Disruptors. 2022. https://doi.org/10.2172/1873907.
    3. Nulwala, H.; Diaz, C.; Medlin, K.; Yan, Z. Compatibilization of Recycled Polypropylene with Polyethylene Blends Via Ionic Liquid to Enhance Mechanical Properties. ECS Meeting Abstracts 2022, MA2022-02 (55), 2094. https://doi.org/10.1149/MA2022-02552094MTGABS.
    4. Nulwala, H.; Zhou, X. Electrochemical Reduction of Active Metals in Aqueous Systems: An Electron Withdrawing Ligand Approach to Deposit Highly Adherent Oxide Layers. ECS Meeting Abstracts 2022, MA2022-02 (23), 975. https://doi.org/10.1149/MA2022-0223975MTGABS.
  • 2021
    1. Vijapur, S. H.; Hall, T.; Garich, H.; Inman, M.; Snyder, S.; Nulwala, H. Ionic Liquid-Assisted Electrochemical Extraction of Oxygen from Lunar Regolith. ECS Meeting Abstracts 2021, MA2021-02 (59), 1754–1754. https://doi.org/10.1149/MA2021-02591754MTGABS/META.
    2. Nulwala, H. B., Zhou, Xu., Chen, S., Hyung K. Universal solvent viscosity Reduction via hydrogen bonding disruptors. 2018. (US-DOE report
  • 2018
    1. Piedrahita, C., Kusuma, V., Nulwala, H. B., & Kyu, T.. Highly conductive, flexible polymer electrolyte membrane based on poly(ethylene glycol) diacrylate-co-thiosiloxane network. Solid State Ionics, 2018, 322, 61–68
    2. Sekizkardes, A. K., Zhou, X., Nulwala, H. B., Hopkinson, D., & Venna, S. R. Ionic cross-linked polyether and silica gel mixed matrix membranes for CO2 separation from flue gas. Separation and Purification Technology, 2018, 191.
    3. Nulwala, H., Mirjafari, A., & Zhou, X.. Ionic liquids and poly(ionic liquid)s for 3D printing – A focused mini-review. European Polymer Journal, 2018, 108.
    4. Hmissa, T., Zhang, X., Dhumal, N. R., McManus, G. J., Zhou, X., Nulwala, H. B., & Mirjafari, A.. Autocatalytic Synthesis of Bifluoride Ionic Liquids by SuFEx Click Chemistry. Angewandte Chemie, 2018, 130(49), 16237–16241.
    5. Nulwala, H. B., Zhou, Xu., Chen, S., & Allcock, H. Lab-scale Development of a Hybrid Capture System with Advanced Membrane, Solvent system, and Process Integration. 2018. (US-DOE report)
  • 2017
    1. Venna, S. R., Spore, A., Tian, Z., Marti, A. M., Albenze, E. J., Nulwala, H. B., Rosi, N. L., Luebke, D. R., Hopkinson, D. P., & Allcock, H. R.. Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles. Journal of Membrane Science, 2017, 535, 103–112.
    2. He, H., Rahimi, K., Zhong, M., Mourran, A., Luebke, D. R., Nulwala, H. B., Möller, M., & Matyjaszewski, K. (2017). Cubosomes from hierarchical self-assembly of poly(ionic liquid) block copolymers. Nature Communications 2017 8:1, 8(1), 1–8.
  • 2016
    1. Siefert, N. S.; Agarwal, S.; Shi, F.; Shi, W.; Roth, E. A.; Hopkinson, D.; Kusuma, V. A.; Thompson, R. L.; Luebke, D. R.; Nulwala, H. B. Hydrophobic Physical Solvents for Pre-Combustion CO2 Capture: Experiments, Computational Simulations, and Techno-Economic Analysis. Int. J. Greenh. Gas Control 2016, 49, 364–371.
    2. Zhou, X., Obadia, M. M., Venna, S. R., Roth, E. A., Serghei, A., Luebke, D. R., Myers, C., Chang, Z., Enick, R., Drockenmuller, E., & Nulwala, H. B.. Highly cross-linked polyether-based 1,2,3-triazolium ion conducting membranes with enhanced gas separation properties. European Polymer Journal, 2016, 84, 65–76.
  • 2015
    1. Watkins, J. D.; Roth, E. A.; Lartey, M.; Albenze, E.; Zhong, M.; Luebke, D. R.; Nulwala, H. B. Ionic Liquid Regioisomers: Structure Effect on the Thermal and Physical Properties. New J. Chem. 2015, 39 (3), 1563–1566.
    2. Venna, S. R.; Lartey, M.; Li, T.; Spore, A.; Kumar, S.; Nulwala, H.; Luebke, D. R.; Rosi, N. L.; Albenze, E. Fabrication of MMMs with Improved Gas Separation Properties Using Externally Functionalized MOF Particles. J. Mater. Chem. A 2015, 3 (9), 5014–5022.
    3. Kusuma, V. A.; Roth, E. A.; Clafshenkel, W. P.; Klara, S. S.; Zhou, X.; Venna, S. R.; Albenze, E.; Luebke, D. R.; Mauter, M. S.; Koepsel, R. R.; et al. Crosslinked Poly(ethylene Oxide) Containing Siloxanes Fabricated through Thiol-Ene Photochemistry. J. Polym. Sci. Part A Polym. Chem. 2015, 53 (13), 1548–1557.
    4. He, H.; Chung, H.; Roth, E.; Luebke, D.; Hopkinson, D.; Nulwala, H.; Matyjaszewski, K. Low Glass Transition Temperature Poly(ionic Liquid) Prepared from a New Quaternary Ammonium Cationic Monomer. Polym. Adv. Technol. 2015, 26 (7), 823–828.
    5. Tian, Z.; Hess, A.; Fellin, C. R.; Nulwala, H.; Allcock, H. R. Phosphazene High Polymers and Models with Cyclic Aliphatic Side Groups: New Structure-Property Relationships. Macromolecules 2015, 48 (13), 4301–4311.
    6. Lartey, M.; Meyer-Ilse, J.; Watkins, J. D.; Roth, E. A.; Bowser, S.; Kusuma, V. A.; Damodaran, K.; Zhou, X.; Haranczyk, M.; Albenze, E.; et al. Branched Isomeric 1,2,3-Triazolium-Based Ionic Liquids: New Insight into Structure-Property Relationships. Phys. Chem. Chem. Phys. 2015, 17 (44), 29834–29843.
    7. Sekizkardes, A. K.; Culp, J. T.; Islamoglu, T.; Marti, A.; Hopkinson, D.; Myers, C.; El-Kaderi, H. M.; Nulwala, H. B. An Ultra-Microporous Organic Polymer for High-Performance Carbon Dioxide Capture and Separation. Chem. Commun. (Camb). 2015, 51 (69), 13393–13396.
    8. Ivanova, A. S.; Brinzer, T.; Roth, E. A.; Kusuma, V. A.; Watkins, J. D.; Zhou, X.; Luebke, D.; Hopkinson, D.; Washburn, N. R.; Garrett-Roe, S.; et al. Eutectic Ionic Liquid Mixtures and Their Effect on CO 2 Solubility and Conductivity. RSC Adv. 2015, 5 (63), 51407–51412.
    9. Watkins, J. D.; Siefert, N. S.; Zhou, X.; Myers, C. R.; Kitchin, J. R.; Hopkinson, D. P.; Nulwala, H. B. Redox-Mediated Separation of Carbon Dioxide from Flue Gas. Energy & Fuels 2015, 29 (11), 7508–7515.
  • 2014
    1. Adzima, B. J.; Taylor, S. C.; He, H.; Luebke, D. R.; Matyjaszewski, K.; Nulwala, H. B. Vinyl-Triazolium Monomers: Versatile and New Class of Radically Polymerizable Ionic Monomers. J. Polym. Sci. Part A Polym. Chem. 2014, 52, 417–423.
    2. He, H.; Li, W.; Lamson, M.; Zhong, M.; Konkolewicz, D.; Hui, C. M.; Yaccato, K.; Rappold, T.; Sugar, G.; David, N. E.; et al. Porous Polymers Prepared via High Internal Phase Emulsion Polymerization for Reversible CO2 Capture. Polymer. 2014, 55, 385–394.
    3. He, H.; Adzima, B.; Zhong, M.; Averick, S.; Koepsel, R.; Murata, H.; Russell, A.; Luebke, D.; Takahara, A.; Nulwala, H.; et al. Multifunctional Photo-Crosslinked Polymeric Ionic Hydrogel Films. Polym. Chem. 2014, 5, 2824–2835.
    4. He, H.; Averick, S.; Roth, E.; Luebke, D.; Nulwala, H.; Matyjaszewski, K. Clickable Poly(ionic Liquid)s for Modification of Glass and Silicon Surfaces. Polymer. 2014. 55, 3330–3338.
    5. Adzima, B.; Venna, S.; Klara, S.; He, H.; Zhong, M.; Mauter, M. S.; Luebke, D. R.; Matyjaszewski, K.; Nulwala, H. Modular Polymerized Ionic Liquid Block Copolymer Membranes for CO2/N2 Separation. J. Mater. Chem. A 2014, 2(21), 7967–7972.
    6. Thompson, R. L.; Shi, W.; Albenze, E.; Kusuma, V. A.; Hopkinson, D.; Damodaran, K.; Lee, A. S.; Kitchin, J. R.; Luebke, D. R.; Nulwala, H. Probing the Effect of Electron Donation on CO2 Absorbing 1,2,3-Triazolide Ionic Liquids. RSC Adv. 2014, 4, 12748.
    7. Yan, F.; Lartey, M.; Jariwala, K.; Bowser, S.; Damodaran, K.; Albenze, E.; Luebke, D. R.; Nulwala, H. B.; Smit, B.; Haranczyk, M. Toward a Materials Genome Approach for Ionic Liquids: Synthesis Guided by Ab Initio Property Maps. J. Phys. Chem. B 2014, 118 (47), 13609–13620.
    8. He, H.; Zhong, M.; Luebke, D.; Nulwala, H.; Matyjaszewski, K. Atom Transfer Radical Polymerization of Ionic Liquid Monomer: The Influence of Salt/counterion on Polymerization. J. Polym. Sci. Part A Polym. Chem. 2014, 52 (15), 2175-2184.
    9. Shi, W.; Thompson, R. L.; Albenze, E.; Steckel, J. A.; Nulwala, H. B.; Luebke, D. R. Contribution of the Acetate Anion to CO2 Solubility in Ionic Liquids: Theoretical Method Development and Experimental Study. J. Phys. Chem. B 2014, 118 (26), 7383–7394.
    10. Shi, W.; Hong, L.; Damodaran, K.; Nulwala, H. B.; Luebke, D. R. Molecular Simulation and Experimental Study of CO2 Absorption in Ionic Liquid Reverse Micelle. J. Phys. Chem. B 2014, 118 (48), 13870.
  • 2013
    1. Allen, J. J.; Schneider, Y.; Kail, B. W.; Luebke, D. R.; Nulwala, H. B.; Damodaran, K. Nuclear Spin Relaxation and Molecular Interactions of a Novel Triazolium-Based Ionic Liquid. J. Phys. Chem. B 2013, 117, 3877–3883.
    2. He, H.; Zhong, M.; Adzima, B.; Luebke, D.; Nulwala, H.; Matyjaszewski, K. A Simple and Universal Gel Permeation Chromatography Technique for Precise Molecular Weight Characterization of Well-Defined Poly(ionic Liquid)s. J. Am. Chem. Soc. 2013, 135, 4227–4230.
    3. Lartey, M.; Gillissen, M.; Adzima, B. J.; Takizawa, K.; Luebke, D. R.; Nulwala, H. B. Synthesis and Reactivity Ratios of Regioisomeric Vinyl-1,2,3-Triazoles with Styrene. J. Polym. Sci. Part A Polym. Chem. 2013, 3359–3364.
    4. Thompson, R.; Damodaran, K.; Luebke, D.; Nulwala, H. Aprotic Heterocyclic Anion Triazolide Ionic Liquids – A New Class of Ionic Liquid Anion Accessed by the Huisgen Cycloaddition Reaction. Synlett 2013, 24, 1093–1096.
    5. Mao, J. X.; Lee, A. S.; Kitchin, J. R.; Nulwala, H. B.; Luebke, D. R.; Damodaran, K. Interactions in 1-Ethyl-3-Methyl Imidazolium Tetracyanoborate Ion Pair: Spectroscopic and Density Functional Study. J. Mol. Struct. 2013, 1038, 12–18.
    6. Yan, F.; Lartey, M.; Damodaran, K.; Albenze, E.; Thompson, R. L.; Kim, J.; Haranczyk, M.; Nulwala, H. B.; Luebke, D. R.; Smit, B. Understanding the Effect of Side Groups in Ionic Liquids on Carbon-Capture Properties: A Combined Experimental and Theoretical Effort. Phys. Chem. Chem. Phys. 2013, 15, 3264–3272.
    7. Mao, J. X.; Lee, A. S.; Kitchin, J. R.; Nulwala, H. B.; Luebke, D. R.; Damodaran, K. Interactions in 1-Ethyl-3-Methyl Imidazolium Tetracyanoborate Ion Pair: Spectroscopic and Density Functional Study. J. Mol. Struct. 2013, 1038, 12–18.
    8. Enick, R. M.; Koronaios, P.; Stevenson, C.; Warman, S.; Morsi, B.; Nulwala, H.; Luebke, D. Hydrophobic Polymeric Solvents for the Selective Absorption of CO2 from Warm Gas Streams That Also Contain H2 and H2O. Energy & Fuels 2013, 27, 6913–6920.
  • 2008-2012
    1. Mao, J. X.; Nulwala, H. B.; Luebke, D. R.; Damodaran, K. Spectroscopic and Computational Analysis of the Molecular Interactions in the Ionic Liquid Ion Pair [BMP]+[TFSI]−. J. Mol. Liq. 2012, 175, 141–147.
    2. Mao, J. X.; Nulwala, H. B.; Luebke, D. R.; Damodaran, K. Spectroscopic and Computational Analysis of the Molecular Interactions in the Ionic Liquid Ion Pair [BMP]+[TFSI]−. J. Mol. Liq. 2012, 175, 141–147.
    3. Zhong, M.; Natesakhawat, S.; Baltrus, J. P.; Luebke, D.; Nulwala, H.; Matyjaszewski, K.; Kowalewski, T. Copolymer-Templated Nitrogen-Enriched Porous Nanocarbons for CO(2) Capture. Chem. Commun. (Camb). 2012, 48, 11516–11518.
    4. Shi, W.; Damodaran, K.; Nulwala, H. B.; Luebke, D. R. Theoretical and Experimental Studies of Water Interaction in Acetate Based Ionic Liquids. Phys. Chem. Chem. Phys. 2012, 14, 15897–15908.
    5. Tang, C. N.; Nulwala, H. B.; Damodaran, K.; Kaur, P.; Luebke, D. R. Tunable Poly(hydroxyl Urethane) from CO2-Based Intermediates Using Thiol-Ene Chemistry. J. Polym. Sci. Part A Polym. Chem. 2011, 49, 2024–2032.
    6. Nulwala, H. B.; Tang, C. N.; Kail, B. W.; Damodaran, K.; Kaur, P.; Wickramanayake, S.; Shi, W.; Luebke, D. R. Probing the Structure-Property Relationship of Regioisomeric Ionic Liquids with Click Chemistry. Green Chem. 2011, 13, 3345.
    7. Nulwala, H.; Burke, D. J.; Khan, A.; Serrano, A.; Hawker, C. J. N -Vinyltriazoles: A New Functional Monomer Family through Click Chemistry. Macromolecules 2010, 43, 5474–5477.
    8. Gerbec, J. A.; Granstrom, J.; Nulwala, H.; Campos, L. M.; Hawker, C. J. Approaches to Solution Deposited Flexible Composite Vapor Barrier Films. Mater. Res. Soc. Symp. Proc. 2010, 1195, No pp. given, Paper #: 1195–B08–26.
    9. Nulwala, H.; Takizawa, K.; Odukale, A.; Khan, A.; Thibault, R. J.; Taft, B. R.; Lipshutz, B. H.; Hawker, C. J. Synthesis and Characterization of Isomeric Vinyl-1,2,3-Triazole Materials by Azide−Alkyne Click Chemistry. Macromolecules 2009, 42, 6068–6074.
    10. Takizawa, K.; Nulwala, H.; Thibault, R. J.; Lowenhielm, P.; Yoshinaga, K.; Wooley, K. L.; Hawker, C. J. Facile Syntheses of 4-Vinyl-1 , 2 , 3-Triazole Monomers by Click Azide / Acetylene Coupling. J. Polym. Sci. Part A Polym. Chem. 2008, 46, 2897–2912.
    11. Takizawa, K.; Nulwala, H.; Hu, J.; Yoshinaga, K.; Hawker, C. J. Molecularly Defined (L)-Lactic Acid Oligomers and Polymers: Synthesis and Characterization. J. Polym. Sci. Part A Polym. Chem. 2008, 46, 5977–5990.
    12. Takizawa, K.; Nulwala, H.; Thibault, R. J.; Lowenhielm, P.; Yoshinaga, K.; Wooley, K. L.; Hawker, C. J. And Click.