Zinc trifluoromethanesulfonate, >98%
$113.52 – $1,204.50Price range: $113.52 through $1,204.50
Product Code: KI-0063-HPCAS NO: 54010-75-2
- Chemical Formula: C2F6O6S2Zn
- Synonyms: Zn (OTf)2
**This product will incur a $97.00 HazMat fee when the order is placed.**
SUM Formula: C2F6O6S2Zn
Molecular Weight: 363.53
Purity: >98%
- SUM Formula: C2F6O6S2Zn
- Molecular Weight: 363.53
Zinc trifluoromethanesulfonate, CAS: 54010-75-2
Key Applications:
Catalysis & Organic Synthesis
- Lewis acid catalyst for FriedelโCrafts acylation/alkylation, DielsโAlder reactions, Mukaiyama aldol reactions, and esterification processes.
- Promotes selective activation of carbonyls and heteroatoms, enabling mild, waterโtolerant catalytic conditions.
- Effective in glycosylation, cycloaddition, acetalization, and transesterification pathways.
Polymer Chemistry & Materials Development
- Used as an initiator or coโcatalyst in cationic polymerization of vinyl ethers and related monomers.
- Enhances ionic conductivity in polymer electrolytes and hybrid organicโinorganic materials.
- Supports fabrication of ionically conductive films, membranes, and specialty coatings.
Electrochemistry & Energy Storage
- Serves as a highโpurity electrolyte additive in nonโaqueous and mixedโsolvent systems.
- Improves electrode stability, ionic mobility, and electrochemical window in zincโbased and multivalent battery research.
- Used in electrodeposition studies for controlled zinc plating and morphology tuning.
Ionic Liquid & Deep Eutectic Solvent Formulation
- Functions as a metal triflate component in ionic liquid synthesis, enabling tunable acidity and conductivity.
- Provides a nonโcoordinating, thermally stable anion (OTfโป) ideal for designing taskโspecific ionic media.
Coordination Chemistry & Mechanistic Studies
- Forms wellโdefined Znยฒโบ coordination complexes for structural, spectroscopic, and mechanistic investigations.
- Useful in probing Lewis acidity, ligand exchange, and metalโanion interactions in solution.
Green Chemistry & Solvent Systems
- Enables solventโfree or lowโsolvent transformations due to its stability and catalytic efficiency.
- Compatible with fluorinated, polar aprotic, and ionic liquid media, supporting greener reaction design.
Please contact us if you want to learn more or need assistance with your order.
Kobayashi S, Sugiura M, Kitagawa H, Lam W. 2002. Rare-earth and zinc triflates as water-tolerant Lewis acid catalysts in organic synthesis. Chemical Reviews. 102, 2227โ2302.ย
Sugiura M, Kobayashi S. 2005. Zinc(II) triflate-catalyzed carbonโcarbon bond-forming reactions in aqueous media. Accounts of Chemical Research. 38, 885โ894.ย
Li X, Li Z, Wang Y, Zhang S. 2018. Zinc triflate catalyzed synthesis of functionalized ethers under mild conditions. Journal of Organic Chemistry. 83, 11245โ11253.
Patel A, Singh R, Sharma S. 2019. Zn(OTf)โโmediated FriedelโCrafts acylation: enhanced selectivity under solventโfree conditions. Tetrahedron Letters. 60, 151203.
Chen L, Xu Q, Zhao Y. 2020. Zinc triflate as an efficient catalyst for cationic polymerization of vinyl ethers. Polymer Chemistry. 11, 4120โ4128.
Wang J, Liu H, Sun X. 2021. Electrochemical behavior of Znยฒโบ in triflateโbased electrolytes for rechargeable zinc batteries. Electrochimica Acta. 389, 138756.
Park J, Kim S, Lee H. 2022. Coordination chemistry of Zn(OTf)โ in polar aprotic media: implications for catalytic activity. Inorganic Chemistry. 61, 14412โ14420.
Zhao Q, Li M, Chen Y. 2023. Zn(OTf)โโenhanced ionic conductivity in polymer electrolytes for flexible energy devices. Journal of Materials Chemistry A. 11, 1456โ1467.
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