Lithium bis(fluorosulfonyl)imide, >99%
$97.65 – $629.79Price range: $97.65 through $629.79
Product Code: KI-0059-UPCAS NO: 171611-11-3
- Chemical Formula: F2LiNO4S2
- Synonyms: Li FSI
Category: Lithium Ion BatteryMetal Salts
SUM Formula: F2LiNO4S2
Molecular Weight: 187.07
Purity: >99%
- SUM Formula: F2LiNO4S2
- Molecular Weight: 187.07
Lithium bis(fluorosulfonyl)imide, CAS: 171611-11-3
Key Applications
Electrolytes in Lithium Batteries
- Widely used as a lithium salt in electrolytes for lithium-ion and lithium-metal batteries.
- Offers higher ionic conductivity compared to LiPFโ, improving rate capability and low-temperature performance.
- Enhances cycling stability and reduces impedance growth in high-voltage cathode systems.
- Provides better thermal stability and hydrolytic resistance, reducing gas generation and safety risks.
Solid-State and Gel Electrolytes
- Compatible with polymer and gel electrolytes, enabling flexible and solid-state battery designs.
- Improves interfacial stability between electrodes and solid electrolytes.
High-Voltage Cathode Systems
- Supports operation with cathodes above 4.3 V, where conventional salts degrade.
- Reduces transition-metal dissolution and mitigates side reactions at elevated voltages.
Lithium Metal and Anode Protection
- Forms stable solid electrolyte interphase (SEI) layers on lithium metal and graphite anodes.
- Helps suppress dendrite growth, improving safety and cycle life in lithium-metal batteries.
Supercapacitors and Hybrid Devices
- Applied in advanced electrolytes for supercapacitors, offering high ionic mobility and wide electrochemical stability windows.
- Enables hybrid energy storage systems combining battery-like and capacitor-like behavior.
Industrial and Research Applications
- Used in research for next-generation energy storage systems, including lithium-sulfur and lithium-air batteries.
- Serves as a benchmark salt for evaluating electrolyte additives and novel solvent systems.
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Cheng, H., Zhu, J., Jin, H., Gao, C., Liu, H., Cai, N., Liu, Y., Zhang, P., & Wang, M. (2021). In situ initiator-free gelation of highly concentrated lithium bis(fluorosulfonyl)imide-1,3-dioxolane solid polymer electrolyte for high performance lithium-metal batteries. Materials Today Energy, 20, 100623.
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Jin, H., Liu, H., Cheng, H., Zhang, P., & Wang, M. (2020). The synergistic effect of lithium bis(fluorosulfonyl)imide and lithium nitrate for high-performance lithium metal anode. Journal of Electroanalytical Chemistry, 874, 114484.
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Huangzhang, E., Zeng, X., Yang, T., Liu, H., Sun, C., Fan, Y., Hu, H., Zhao, X., Zuo, X., & Nan, J. (2022). A localized high-concentration electrolyte with lithium bis(fluorosulfonyl) imide (LiFSI) salt and F-containing cosolvents to enhance the performance of Li||LiNi0.8Co0.1Mn0.1O2 lithium metal batteries. Chemical Engineering Journal, 439, 135534.
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